Masterminds are considered geniuses among geniuses; in other words, they are among the most intelligent beings in existence and are characterized by a personality in which they will plan things to amazing lengths and always have a backup plan. They are often extremely difficult to catch or defeat due to their incredibly complex schemes.
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A
- Abbott Hayes
- Abigail Williams (Murdered: Soul Suspect)
- Ace (The Powerpuff Girls)
- Adam (Buffyverse)
- Adam Barlow
- Adolf Hitler (The Twilight Zone)
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- Agatha Trunchbull
- Agent Kruger
- Agent Orange (Marvel Cinematic Universe)
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- Aggregor
- Ajax (X-Men Movies)
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- Akihiro Kurata
- Aku
- Akumatized villains
- Al-G Rhythm
- Alameda Slim
- Alastor (Hazbin Hotel)
- Albert Wesker
- Alec Trevelyan
- Aleema Keto
- Alejandro Gutierrez
- Alex Wesker
- Alonzo Harris
- Alternates
- Amon Goeth
- Andy Hunter
- Anton LaVey (American Horror Story)
- April Troost
- Archibald Snatcher
- Aresia
- Ariel Augustus
- Arjen Rudd
- Arthur (Wreck-It Ralph)
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- Arthur Slugworth (Wonka)
- Ash Landers
- August Walker
- Auric Goldfinger
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B
- Babidi
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- Bane (Nolanverse)
- Bardock
- Baron Corbin
- Barracuda (Marvel)
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- Belle Fontiere
- Bibidi
- Big Jack Horner
- Bill Cipher
- Bill Sykes
- Billy Loomis
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- Boingo
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- Boogie Man
- Botticelli Remorso
- Bowser
- Bowser (The Super Mario Bros. Movie)
- Bree Blackburn
- Bria
- Brokenstar
- Broodwing
- Burt Hartman
- Byleth Eisner
C
- Cackletta
- Captain Armando Salazar
- Captain Chantel DuBois
- Captain Cold
- Captain Kuro
- Carl King (Emmerdale)
- Carnage (Marvel)
- Cat Blanc
- Cat R. Waul
- Caturamon
- Chalis
- Chameleon (T.U.F.F. Puppy)
- Chaos
- Charles Rane
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- Chester Hardwick
- Chester V
- Chucky
- Circus Baby
- Claude Frollo
- Claudius
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- Clone Troopers
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- Colleen McCandless
- Constantine
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- Crocodile (One Piece)
- Cruella De Vil (Disney)
- Cyrus Grissom
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- D-Reaper
- Dag
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- Dark Danny
- Dark Samus
- Darkonda
- Darkseid (DC Animated Universe)
- Darth Maul
- Darth Vader
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- David Hagan
- Davros
- Death Adder (Golden Axe)
- Deviot
- Diane Simmons
- Dick Finley
- Diesel 10
- Dio Brando
- Dirty Rat
- Doctor Doom (2015 Film)
- Doctor Octopus (Spider-Man Films)
- Doctor Octopus(Marvel Comics)
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- Dollmaker
- Dr Evil
- Dr. Alexander Isaacs
- Dr. Blowhole
- Dr. Calico
- Dr. Carl Mortner
- Dr. Charles Nichols
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- Dr. Eggman (Archie Comics)
- Dr. Gelee
- Dr. Henry Miller
- Dr. Ivo "Eggman" Robotnik
- Dr. Kulik
- Dr. Nefarious Tropy (original)
- Dr. Neo Cortex
- Dr. Robotnik (Archie Comics)
- Dr. Robotnik (Paramount Film Series)
- Dr. Wily (Mega Man)
- Drago Bludvist
- Drago's Bewilderbeast
- Dreadpool
- Duchess (Foster's Home for Imaginary Friends)
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- Edgar The Bug
- Eggman Nega
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- Ein
- El Macho
- Elder Princess Shroob
- Eleanor (Fazbear Frights)
- Elio
- Elliot Carver
- Emilio Largo
- Emperor Palpatine
- Emperor Zurg (Buzz Lightyear of Star Command)
- Ennard
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- Ernst Stavro Blofeld
- Ernst Stavro Blofeld (Reboot Series)
- Esther Coleman
- Eustace Strych
- Evelyn Deavor
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