Villains who made their debut between 1990 and 1999.
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Eric Cartman
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- Sam Garland
- Scampi
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- Shauna Krawly
- She-Demon (Hercules: The Legendary Journeys)
- Sid Phillips
- Simon the Monster Hunter
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- SkullGreymon
- Slappy the Dummy
- Smithy
- Soraya Montenegro
- SpaceGodzilla
- Spice (Batman)
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- Stu Macher
- Sugar (Batman)
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