Cruella De Vil

Cruella De Vil is the main antagonist of Disney's One Hundred and One Dalmatians, as well as its sequels and live-action remake. Cruella is a wealthy heiress and former friends with Anita Radcliffe.

One Hundred and One Dalmatians
When the pet dalmatians are going to have puppies, Cruella quickly comes to visit so she can take the puppies away to use as fur coats. She starts smoking, making the room fill with smoke. She leaves after since the Dalmatians haven't given birth yet.